Metallophthalocyanines as potent catalysts for cyclopropanation of olefins with ethyldiazoacetate
IR@IIP: CSIR-Indian Institute of Petroleum, Dehradun
View Archive Info| Field | Value | |
| Creator |
Sharma, Vishal B
Jain, Suman L Sain, Bir |
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| Date |
2009-06-18T11:37:35Z
2009-06-18T11:37:35Z 2009-06-18T11:37:35Z |
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| Identifier |
http://hdl.handle.net/123456789/153
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| Description |
Copper, manganese and iron phthalocyanines were found to be highly efficient catalysts for cyclopropanation of olefins using
ethyldiazoacetate as carbene precursor. In general copper(II)-phthalocyanine was found to be the most active catalyst followed by
the Mn(II)Pc and Fe(II)Pc. Ni(II)Pc and Co(II)Pc were found to be the less active catalysts for this reactions.
KEY WORDS: metallophthalocyanine; carbene; cyclopropanation; diazoesters; olefin.
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| Language |
en_US
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| Subject |
Metallophthalocyanine
Olefin Cyclopropanation Diazoesters |
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| Title |
Metallophthalocyanines as potent catalysts for cyclopropanation of olefins with ethyldiazoacetate
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| Type |
Article
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