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Chemo-, regio-, and stereoselective Heck–Matsuda arylation of allylic alcohols under mild conditions

IR@IICB: CSIR-Indian Institute of Chemical Biology, Kolkata

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Title Chemo-, regio-, and stereoselective Heck–Matsuda arylation of allylic alcohols under mild conditions
 
Creator Chaudhari, Tohasib Yusub
Hossian, Asik
Manna, Manash Kumar
Jana, Ranjan
 
Subject Chemistry
 
Description Heck arylation with allylic alcohol is extremely challenging due to chemo-, regio-, and stereoselective scrambling. Here we report a mild protocol for the alcohol selective β- and α-arylation of allylic and cinnamyl alcohols respectively with aryldiazonium salts. The steric and electronic parameters of the alkene play a prominent role in the regioselectivity
 
Date 2015
 
Type Article
PeerReviewed
 
Format application/pdf
application/pdf
 
Identifier http://www.eprints.iicb.res.in/2246/1/ORGANIC_%26_BIOMOLECULAR_CHEMISTRY__V.__13__(_17_)_4841%2D4845_;2015[89].pdf
http://www.eprints.iicb.res.in/2246/2/ORGANIC_%26_BIOMOLECULAR_CHEMISTRY__V.__13__(_17_)_4841%2D4845_;2015[89].pdf
Chaudhari, Tohasib Yusub and Hossian, Asik and Manna, Manash Kumar and Jana, Ranjan (2015) Chemo-, regio-, and stereoselective Heck–Matsuda arylation of allylic alcohols under mild conditions. Organic & Biomolecular Chemistry, 13 (17). pp. 4841-4845.
 
Relation http://dx.doi.org/10.1039/c5ob00235d
http://www.eprints.iicb.res.in/2246/