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Surfactant-Modified Zeolite as a Slow Release Fertilizer for Phosphorus

IR@NEERI: National Environment Engineering Research Institute

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Title Surfactant-Modified Zeolite as a Slow Release Fertilizer for Phosphorus
 
Creator Bansiwal, Amit Kumar
Rayalu, Sadhana Suresh
Labhasetwar, Nitin Kumar
Juwarkar, Asha Ashok
Devotta, Sukumar
 
Subject Agriculture
Chemistry, Chemical Technology
 
Description The feasibility of using surfactant-modified zeolite(SMZ)as a carrier for fertilizer and for slow release of phosphorus (P)was investigated. Zeolite-A was modified by using hexadecytrimethylammonium bromide, a cationic surfactant, to modify its surface to increase its capacity to retainanion, namely, infrared, and scanning electron microscopy to study the effect of surfactant modification. Zeolite-A and SMZ were then subjected to P loading by treating them with fertilizer(KH2PO4). It was observed that the P loading on SMZ increased by a factor of 4.9 as compared to the unmodified Zeolite-A. A comparative study of the release of P from fertilizer-loaded unmodified zeolite-A and SMZ and from solid KH2PO4 was performed using the conatant flow percolation reactor. The result show that the P supply from fertilizer-loaded SMZ was available even after 1080 h of continuous percolation, whwreas P from KH2PO4 was exhausted within 264 h. The result indicate that SMZ is a good sorbent for PO4, and a slow release of P was achievable. These properties suggest that SMZ has a great potential as the fertilizer carrier for slow relese of P.
 
Publisher American Chemical Society
 
Date 2006
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://neeri.csircentral.net/19/1/bansiwal_2006.pdf
Bansiwal, Amit Kumar and Rayalu, Sadhana Suresh and Labhasetwar, Nitin Kumar and Juwarkar, Asha Ashok and Devotta, Sukumar (2006) Surfactant-Modified Zeolite as a Slow Release Fertilizer for Phosphorus. Journal of Agricultural and Food Chemistry (54). pp. 4773-4779.
 
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