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Influence of magnetron configurations on the structure and properties of room temperature sputtered ZnO thin films

IR@CGCRI: CSIR-Central Glass and Ceramic Research Institute, Kolkata

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Title Influence of magnetron configurations on the structure and properties of room temperature sputtered ZnO thin films
 
Creator Godiwal, Rahul
Gangwar, Amit Kumar
Jaiswal, Jyoti
Vashishtha, Pargam
Hossain, Modassar
Pal, Prabir
Gupta, Govind
Singh, Preetam
 
Subject Engineering Materials
 
Description Under the unbalanced magnetron (UBM) sputtering process, not only the plasma is confined near the target like in the conventional balanced magnetron (BM) sputtering process, but also extends towards the substrate and support the ion-assisted deposition (surface of thin films is bombarded by energetic Ar+ ions during the sputtering process). Here, we report the influence of magnetron configurations on the structure and properties of room temperature sputtered ZnO thin films while keeping other process parameters fixed. The UBM configuration has significantly improved various properties of ZnO thin films in comparison to the BM configuration. The crystalline quality with dominant orientation (002) and uniform distribution of grains is observed while an increase in the band gap from 3.25 eV (BM) to 3.33 eV (UBM) is obtained. The lower defects as investigated from Zn2p and O1s core level XPS spectra, which is well supported by Photoluminescence measurements. In addition to that, surface hydrophobicity has been increased from 121.2 degrees (BM) to 125.5 degrees (UBM). Thus, the unbalanced magnetron configuration in the sputtering process significantly enhanced the structural, optical and surface properties of ZnO thin films even at room temperature and low plasma power without any post annealing treatments, which is highly desired for the device fabrication.
 
Publisher IOP Publishing
 
Date 2021-01
 
Type Article
PeerReviewed
 
Identifier Godiwal, Rahul and Gangwar, Amit Kumar and Jaiswal, Jyoti and Vashishtha, Pargam and Hossain, Modassar and Pal, Prabir and Gupta, Govind and Singh, Preetam (2021) Influence of magnetron configurations on the structure and properties of room temperature sputtered ZnO thin films. Physica Scripta, 96 (1). Art No- 01581. ISSN 0031-8949
 
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