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Confinement creates a 9 GPa ambience: emergence of cristobalite phases in a silica film

IR@CGCRI: CSIR-Central Glass and Ceramic Research Institute, Kolkata

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Title Confinement creates a 9 GPa ambience: emergence of cristobalite phases in a silica film
 
Creator Pramanik, Subrata
Ghosh, Jiten
Chanda, Dipak Kumar
Mukhopadhyay, Mrinmay Kumar
Datta, Alokmay
 
Subject Engineering Materials
 
Description We present here the results of the x-ray fluorescence (XRF), x-ray photoelectron spectroscopy (XPS), Field Emission Scanning Electron Microscopy (FESEM) and Energy Dispersive Analysis of x-rays (EDAX), x-ray Reflectivity (XRR), Secondary Ion Mass spectroscopy (SIMS) and x-ray Diffraction (XRD) studies of silica films spin-coated from a Tetraethyl Orthosilicate (TEOS) precursor on native and hydrophilized Al substrates. It is observed that the substrates are mainly porous (porosity similar to 33%) AlO(OH), there is a diffuse interlayer of highly porous (porosity similar to 90%) AlO(OH), essentially a modification of the substrate, and a top layer of silica composed of nanocrystals with in-plane dimensions of 100-300 nm and thickness of 2.5 nm with a sharply defined silica-hydrated alumina interface. The silica nanocrystals were found in the metastable high pressure cristobalite phases with the tetragonal or alpha-phase co-existing in its low (0.77 GPa) and high (9 GPa) pressure structures. This indicates a high normal stress developed from the confinement and provides a basis for the quantitative assessment of the confinement force, which comes out to be higher in value than the van der Waals force but weaker than the Hydrogen bonding force.
 
Publisher IOP Publishing
 
Date 2021
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cgcri.csircentral.net/5252/1/subrata.pdf
Pramanik, Subrata and Ghosh, Jiten and Chanda, Dipak Kumar and Mukhopadhyay, Mrinmay Kumar and Datta, Alokmay (2021) Confinement creates a 9 GPa ambience: emergence of cristobalite phases in a silica film. Materials Research Express , 8 (6). Art No-066403. ISSN 2053-1591
 
Relation http://cgcri.csircentral.net/5252/