Intramolecular Heck reaction strategy for the synthesis of functionalised tetrahydroanthracenes: a facile formal total synthesis of the linear abietane diterpene, umbrosone
IR@IICB: CSIR-Indian Institute of Chemical Biology, Kolkata
View Archive Info| Field | Value | |
| Title |
Intramolecular Heck reaction strategy for the synthesis
of functionalised tetrahydroanthracenes: a facile formal
total synthesis of the linear abietane diterpene, umbrosone
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| Creator |
Sengupta, Sujaya
Mukhopadhyay, Ranjan Achari, Basudeb Banerjee, Asish Kr |
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| Subject |
Chemistry
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| Description |
Rapid annulation employing an intramolecular Heck reaction yielded the functionalised 1,1,10-trimethyl-6-methoxy-
1,2,3,4-tetrahydroanthracene 4a, a key intermediate for the linear diterpenoid quinone umbrosone (1), and the related compounds
4b–d. A similar strategy was also successfully adopted for the synthesis of the 9-methyl tetrahydroanthracene ester 5 and the tetrahydrodibenzo[
a,d]cycloheptene ester 6.
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| Publisher |
Elsevier
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| Date |
2005
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://www.eprints.iicb.res.in/554/1/TETRAHEDRON_LETTERS___46(_9_)1515%2D1519_;2005[93].pdf
Sengupta, Sujaya and Mukhopadhyay, Ranjan and Achari, Basudeb and Banerjee, Asish Kr (2005) Intramolecular Heck reaction strategy for the synthesis of functionalised tetrahydroanthracenes: a facile formal total synthesis of the linear abietane diterpene, umbrosone. Tetrahedron, 46 (9). pp. 1515-1519. |
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| Relation |
http://dx.doi.org/0.1016/j.tetlet.2005.01.021
http://www.eprints.iicb.res.in/554/ |
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