Allylic Hydroxylation Through Acid Catalysed Epoxy Ring Opening of Betulinic Acid Derivatives
IR@IICB: CSIR-Indian Institute of Chemical Biology, Kolkata
View Archive Info| Field | Value | |
| Title |
Allylic Hydroxylation Through Acid
Catalysed Epoxy Ring Opening of Betulinic
Acid Derivatives
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| Creator |
Pramanick, Swapan
Mandal, Suparna Mukhopadhyay, Sibabrata |
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| Subject |
Chemistry
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| Description |
Acid catalysed epoxy ring opening of several lupane type triterpenoids leads
to unusual allylic hydroxylation. The reaction involves the formation of epoxide by
m-chloroperbenzoic acid followed by the treatment of mineral acid. The simple
methodology finds utility to introduce a hydroxyl function at the allylic position in
these triterpenoids, which is otherwise quite difficult.
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| Date |
2005
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://www.eprints.iicb.res.in/586/1/SYNTHETIC_COMMUNICATIONS__35_(16)_2143%2D2148;2005[110].pdf
Pramanick, Swapan and Mandal, Suparna and Mukhopadhyay, Sibabrata (2005) Allylic Hydroxylation Through Acid Catalysed Epoxy Ring Opening of Betulinic Acid Derivatives. Synthetic Communications, 35 (16). pp. 2143-2148. |
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| Relation |
http://dx.doi.org/10.1080/00397910500180568
http://www.eprints.iicb.res.in/586/ |
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