Fe-HCl: An Efficient Reagent for Deprotection of Oximes as well as Selective Oxidative Hydrolysis of Nitroalkenes and Nitroalkanes to Ketones
IR@IICB: CSIR-Indian Institute of Chemical Biology, Kolkata
View Archive Info| Field | Value | |
| Title |
Fe-HCl: An Efficient Reagent for
Deprotection of Oximes as well as Selective
Oxidative Hydrolysis of Nitroalkenes and
Nitroalkanes to Ketones
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| Creator |
Pradhan, Prasun K
Dey, Sumit Jaisankar , P Giri, V S |
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| Subject |
Chemistry
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| Description |
Fe-HCl mixture was found to selectively perform oxidative hydrolysis of the
nitroalkenes 1a–j and nitroalkanes 2a–j to the ketones 3a–j. Also, the reagent was
observed to deprotect the oximes 7a–j to carbonyl compounds 8a–j in excellent yields.
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| Date |
2005
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://www.eprints.iicb.res.in/587/1/SYNTHETIC_COMMUNICATIONS_35_(7_)913%2D922;2005[111].pdf
Pradhan, Prasun K and Dey, Sumit and Jaisankar , P and Giri, V S (2005) Fe-HCl: An Efficient Reagent for Deprotection of Oximes as well as Selective Oxidative Hydrolysis of Nitroalkenes and Nitroalkanes to Ketones. Synthetic Communications, 35 (7). pp. 913-922. |
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| Relation |
http://dx.doi.org/10.1081/SCC-200051681
http://www.eprints.iicb.res.in/587/ |
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