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Europium triflate: An efficient, cost-effective and recyclable solid acid catalyst for highly chemoselective allylation of aldehydes

IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)

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Field Value
 
Creator Kumbhare, Ravindra M
Sridhar, M
 
Date 2011-12-07T12:18:08Z
2011-12-07T12:18:08Z
2011-12
 
Identifier 0975-0983(Online); 0376-4699(Print)
http://hdl.handle.net/123456789/13217
 
Description 1774-1778
Aldehydes undergo smooth nucleophilic addition with allyl-n-tributylstannane in the presence of europium triflate under extremely mild reaction conditions to afford the corresponding homoallylic alcohols in excellent yields with high chemoselectivity. The catalyst can be recovered by simple filtration and can be recycled in subsequent reactions.
 
Language en_US
 
Publisher NISCAIR-CSIR, India
 
Rights <img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
 
Source IJC-B Vol.50B(12) December 2011]
 
Subject Europium triflate
Allyltributylstannane
Aldehyde
Homoallylic alcohols
 
Title Europium triflate: An efficient, cost-effective and recyclable solid acid catalyst for highly chemoselective allylation of aldehydes
 
Type Article