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Synthesis of chiral cis- and trans-furo[3,2-c][2]benzoxocines from D-glucose by regioselective 8-endo aryl radical cyclisation

IR@IICB: CSIR-Indian Institute of Chemical Biology, Kolkata

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Title Synthesis of chiral cis- and trans-furo[3,2-c][2]benzoxocines from D-glucose by regioselective 8-endo aryl radical cyclisation
 
Creator Nandi, Aniruddha
Mukhopadhyay, Ranjan
Chattopadhyay, Partha
 
Subject Chemistry
 
Description A simple chiral synthesis of cis- and trans-furo[3,2-c][2]benzoxocines 8a–d and 9a–d through a regioselective 8-endo-trig aryl radical cyclisation of the respective 5,6-dideoxy--xylo-hex-5-enofuranosides 6a–d and 5,6-dideoxy--ribo-hex-5-enofuranosides 7a–d with tributyltin hydride is described.
 
Date 2001
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://www.eprints.iicb.res.in/881/1/JOURNAL_OF_THE_CHEMICAL_SOCIETY%2DPERKIN_TRANSACTIONS_1%2C_24%2C_3346%2D3351%2C2001[75].pdf
Nandi, Aniruddha and Mukhopadhyay, Ranjan and Chattopadhyay, Partha (2001) Synthesis of chiral cis- and trans-furo[3,2-c][2]benzoxocines from D-glucose by regioselective 8-endo aryl radical cyclisation. Journal of Chemical Society- Perkin Transactions, 1 (24). pp. 3346-3351.
 
Relation http://dx.doi.org/10.1039/B107886K
http://www.eprints.iicb.res.in/881/