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Stereoselective synthesis of homoallyl nitroalkane derivatives via base-promoted regioselective decarboxylation in Baylis-Hillman derivatives

IR@CDRI: CSIR-Central Drug Research Institute, Lucknow

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Field Value
 
Creator Nayak, Maloy
Batra, Sanjay
 
Date 2010-03-04T06:15:42Z
2010-03-04T06:15:42Z
2009
 
Identifier Eur. J. Org. Chem. 2009, 3505–3507
http://hdl.handle.net/123456789/525
 
Description The regioselective decarboxylation during the saponification of the nitroalkanoates synthesized from the Baylis-Hillman acetates of acrylates to stereoselectively afford homoallyl nitroalkane is described. In contrast the similar nitroalkanoates derived from the Baylis-Hillman acetates of acrylonitrile gave bis allyl nitroalkanes.
 
Format 108505 bytes
application/pdf
 
Language en
 
Relation CDRI Communication Number 7756
 
Subject Homoallyl nitroalkane
regioselective
Baylis-Hillman
decarboxylation
bis-allylnitroalkane
 
Title Stereoselective synthesis of homoallyl nitroalkane derivatives via base-promoted regioselective decarboxylation in Baylis-Hillman derivatives
 
Type Article