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Dimeric Rh(III) Complex Stabilized by Hydrogen Bonding: Building Block of a Nanoporous Supramolecular Assembly

IR@NEIST: CSIR-North East Institute of Science and Technology, Jorhat

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Field Value
 
Title Dimeric Rh(III) Complex Stabilized by Hydrogen Bonding: Building Block of a Nanoporous Supramolecular Assembly
 
Creator Sharma, B J
Dutta, D K
 
Subject Material Science
 
Description The dimeric units [RhCl2(Hhmp)(hmp)]2, where Hhmp and hmp are 2-(hydroxymethyl)pyridine and anionic deprotonated ligand, respectively, is formed by strong hydrogen bonding interactions between pairs of Hhmp and hmp ligands that act as building blocks and self-assemble remarkably through aromatic π-π and CH/-π interactions to generate a nanoporous supramolecular structure exhibiting permanent porosity and selective adsorption properties.
 
Publisher ACS
 
Date 2009-03
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://neist.csircentral.net/173/1/2697.pdf
Sharma, B J and Dutta, D K (2009) Dimeric Rh(III) Complex Stabilized by Hydrogen Bonding: Building Block of a Nanoporous Supramolecular Assembly. Crystal Growth and Design, 9 (4). pp. 1643-1645.
 
Relation http://neist.csircentral.net/173/