Flexible and Simple Route for the Stereoselective Synthesis of Trisubstituted g-Butyrolactones:Total Sysnthesis(+)-Blastomycinone and its Analogs
IR@IICT: CSIR-Indian Institute of Chemical Technology, Hyderabad
View Archive Info| Field | Value | |
| Creator |
RadhaKrishna, P
Reddy, V.V.R Sharma, G.V.M |
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| Date |
2008-12-15T11:08:45Z
2008-12-15T11:08:45Z 2004 |
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| Identifier |
Synthesis-Stuttgart,Vol.0, 2107-2114p
http://hdl.handle.net/123456789/54 |
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| Description |
A flexible route for the stereoselective synthesis of trisubstituted g-butyrolactones and its analogs, is devised by the sharpless asymmetric epoxidation and the regioselective ring opening reation with dibutylcopper lithium and the key steps to introduce the requisite alkyl chain.
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| Subject |
(+)-blastomycinone
(-)-3-epi-blastomycinone Sharpless asymmetric epoxidation Dibutylcopper lithium Witting olefination |
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| Title |
Flexible and Simple Route for the Stereoselective Synthesis of Trisubstituted g-Butyrolactones:Total Sysnthesis(+)-Blastomycinone and its Analogs
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| Type |
Article
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