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Influence of ZnO on the crystallization kinetics and properties of diopside-Ca-Tschermak based glasses and glass-ceramics

IR@CGCRI: CSIR-Central Glass and Ceramic Research Institute, Kolkata

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Title Influence of ZnO on the crystallization kinetics and properties of diopside-Ca-Tschermak based glasses and glass-ceramics
 
Creator Goel, Ashutosh
Tulyaganov, Dilshat U
Shaaban, Essam R
Basu, Rajendra Nath
Ferreira, Jose M F
 
Subject Processing Science
 
Description We report on the influence of ZnO on the structural, thermal, and crystallization behavior of the diopside-Ca-Tschemak based glasses, and on the processing, microstructure, and the properties of the sintered glass ceramics. Four glasses with nominal compositions of CaMg(0.8)Al(0.4)Si(1.8)O(6), CaMg(0.75)Zn(0.05)Al(0.4)Si(1.8)O(6), CaMg(0.70)Zn(0.10)Al(0.4)Si(1.8)O(6), and CaMg(0.60)Zn(0.20)Al(0.4)Si(1.8)O(6) were obtained by melting at 1580 degrees C for 1 h. Structural and thermal behavior of the glasses was investigated by Fourier-transform infrared spectroscopy, density measurements, dilatometry, and differential thermal analysis. Nonisothermal crystallization kinetics has been employed to study the crystallization mechanism in the glasses. Sintering, crystallization, microstructure, and properties of the glass ceramics were investigated under nonisothermal heating conditions in the temperature range of 850-1000 degrees C. (c) 2008 American Institute of Physics.
 
Publisher American Institute of Physics
 
Date 2008-08
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cgcri.csircentral.net/329/1/J_Appl_Phys_104_(2008)_043529.pdf
Goel, Ashutosh and Tulyaganov, Dilshat U and Shaaban, Essam R and Basu, Rajendra Nath and Ferreira, Jose M F (2008) Influence of ZnO on the crystallization kinetics and properties of diopside-Ca-Tschermak based glasses and glass-ceramics. Journal of Applied Physics, 104 (4). ISSN 0021-8979
 
Relation http://cgcri.csircentral.net/329/