One novel racemic Cu-Co cyano-bridged complex: synthesis, characterization, crystal structure, and magnetic properties
IR@CGCRI: CSIR-Central Glass and Ceramic Research Institute, Kolkata
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| Title |
One novel racemic Cu-Co cyano-bridged complex: synthesis, characterization, crystal structure, and magnetic properties
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| Creator |
Roy Choudhury, C
Dey, S K Mitra, S Mondal, N Ribas, J Malik, K M A |
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| Subject |
Microstructure and Characterization
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| Description |
One novel racemic Cu–Co cyano-bridged complex [C38H38CoCu2N14O]+[C22H18CoCuN10]−·7H2O where [L = N,N′-bis(2-pyridylmethylene)butane-1,4-diamine] has been prepared and characterized by elemental analyses, spectroscopic study, single crystal X-ray crystallography, and variable temperature magnetic susceptibility measurements. The compound crystallises as a 57/43 racemic twin and contains two different, one binuclear and one trinuclear, complex species. A low temperature magnetic susceptibility measurement showed the existence of very weak antiferromagnetic interactions.
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| Date |
2004
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| Type |
Article
PeerReviewed |
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| Identifier |
Roy Choudhury, C and Dey, S K and Mitra, S and Mondal, N and Ribas, J and Malik, K M A (2004) One novel racemic Cu-Co cyano-bridged complex: synthesis, characterization, crystal structure, and magnetic properties. Bulletin of the Chemical Society of Japan, 77 (5). pp. 959-964. ISSN 0009-2673
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| Relation |
http://cgcri.csircentral.net/568/
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