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Annealing behavior of silver, copper, and silver-copper nanoclusters in a silica matrix synthesized by the sol-gel technique

IR@CGCRI: CSIR-Central Glass and Ceramic Research Institute, Kolkata

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Title Annealing behavior of silver, copper, and silver-copper nanoclusters in a silica matrix synthesized by the sol-gel technique
 
Creator De, Goutam
Gusso, M
Tapfer, L
Catalano, M
Gonella, F
Mattei, G
Mazzoldi, P
Battaglin, G
 
Subject Microstructure and Characterization
 
Description Silver, copper, and mixed silver–copper nanocluster-doped silica thin layers were prepared by the sol-gel process. Samples were heat treated in different annealing atmospheres ~air, argon, or 5%H2–95%N2! in the temperature range 500–1100 °C. Specimens were characterized by optical absorption spectroscopy, Rutherford backscattering spectrometry, x-ray diffraction, and transmission electron microscopy. Cluster growth and dissolution, as well as migration of metal atoms towards the sample surface, with a subsequent evaporation, were observed to occur at temperatures that depend on the annealing atmosphere. In the mixed silver–copper system, the formation of Ag–Cu phase-separated clusters was observed.
 
Publisher American Institute of Physics
 
Date 1996-12
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cgcri.csircentral.net/1708/1/goutam2.pdf
De, Goutam and Gusso, M and Tapfer, L and Catalano, M and Gonella, F and Mattei, G and Mazzoldi, P and Battaglin, G (1996) Annealing behavior of silver, copper, and silver-copper nanoclusters in a silica matrix synthesized by the sol-gel technique. Journal of Applied Physics, 80 (12). pp. 6734-6739. ISSN 0021-8979
 
Relation http://cgcri.csircentral.net/1708/