Carbohydrate Nitrone and Nitrile Oxide Cycloaddition Approach to Chiral Sulfur Heterocycles and Nucleosides
IR@IICB: CSIR-Indian Institute of Chemical Biology, Kolkata
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Title |
Carbohydrate Nitrone and Nitrile Oxide Cycloaddition Approach to Chiral Sulfur
Heterocycles and Nucleosides
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Creator |
Mukherjee, Subhrangshu
Mandal, Sukhendu B Bhattacharjya, Anup |
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Subject |
Chemistry
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Description |
S-Alkenyl and -alkynyl carbohydrate derivatives were prepared from 1,2 : 5,6-O-diisopropylidene-a-
D-allofuranose. Nitrones and nitrile oxides generated from these derivatives led to the formation of 6,
7, and 11-membered chiral sulfur heterocycles fused to isoxazolidine, isoxazoline and isoxazole rings.
Some of these sulfur heterocycles were converted to nucleosides. The 11-memebered sulfur compound
was found to gelate hydrocarbon solvents.
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Date |
2012
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Type |
Article
PeerReviewed |
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Format |
application/pdf
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Identifier |
http://www.eprints.iicb.res.in/1674/1/RSC_ADVANCES___2_(_24_)_8969%2D8978;2012[146].pdf
Mukherjee, Subhrangshu and Mandal, Sukhendu B and Bhattacharjya, Anup (2012) Carbohydrate Nitrone and Nitrile Oxide Cycloaddition Approach to Chiral Sulfur Heterocycles and Nucleosides. RSC Advances, 2 (24). pp. 8969-8978. |
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Relation |
http://dx.doi.org/10.1039/c2ra20689g
http://www.eprints.iicb.res.in/1674/ |
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