Nickel Phthalocyanine Assisted Highly Efficient and Selective Carbonyl Reduction in Polyethylene Glycol-400
IR@IHBT: CSIR-Institute of Himalayan Bioresource Technology, Palampur
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Title |
Nickel Phthalocyanine Assisted Highly Efficient and Selective
Carbonyl Reduction in Polyethylene Glycol-400
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Creator |
Verma , Praveen Kumar
Sharma, Upendra Kumar, Neeraj Bala, Manju Kumar , Vishal Singh , Bikram |
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Subject |
Natural Product Chemistry
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Description |
Nickel phthalocyanine with polyethylene glycol-
400 is described as a reusable green catalytic system
for highly chemo- and regioselective reduction of carbonyl
compounds to corresponding alcohols at room temperature.
The catalytic system showed wide substrate scope covering
aromatic, hetero aromatic and aliphatic carbonyl compounds
with high turnover number and frequency. In the
present study, 1,3- and 1,4-benzenedicarbaldehydes have
been regioselectively reduced to corresponding alcohols
for the first time. The catalyst was reused up to seven times
without any significance loss in activity.
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Date |
2012
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Type |
Article
PeerReviewed |
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Format |
application/pdf
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Identifier |
http://ihbt.csircentral.net/1225/1/30_Nickel.pdf
Verma , Praveen Kumar and Sharma, Upendra and Kumar, Neeraj and Bala, Manju and Kumar , Vishal and Singh , Bikram (2012) Nickel Phthalocyanine Assisted Highly Efficient and Selective Carbonyl Reduction in Polyethylene Glycol-400. Catalysis Letters, 142. pp. 907-913. |
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Relation |
http://ihbt.csircentral.net/1225/
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