Solid supported Pd(0): an efficient recyclable heterogeneous catalyst for chemoselective reduction of nitroarenes
IR@IHBT: CSIR-Institute of Himalayan Bioresource Technology, Palampur
View Archive Info| Field | Value | |
| Title |
Solid supported Pd(0): an efficient recyclable heterogeneous catalyst for
chemoselective reduction of nitroarenes
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| Creator |
Shil, Arun K
Sharma, Dharminder Guha, Nitul Ranjan Das, Pralay |
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| Subject |
Natural Product Chemistry
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| Description |
Solid supported palladium(0) (SS-Pd) catalyzed highly chemoselective reduction of nitroarenes to the
corresponding anilines was accomplished under a milder reaction condition. This catalyst showed high
compatibility with various reducing agents (NaBH4, Et3SiH, and NH2NH2∙H2O) and a large number of
reducible functional groups such as sulfonamide, amides, carboxylic acid, ester, alcohol, halide, hetero
cycle, nitrile, alkene, carbonyl, O-benzyl, and N-benzyl were tolerated. Most of the reactions were clean
and high yielding. The SS-Pd catalyst could be recycled up to seven runs without significant loss of
activity
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| Date |
2012
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://ihbt.csircentral.net/1233/1/37_Solid_supported_Rh.pdf
Shil, Arun K and Sharma, Dharminder and Guha, Nitul Ranjan and Das, Pralay (2012) Solid supported Pd(0): an efficient recyclable heterogeneous catalyst for chemoselective reduction of nitroarenes. Tetrahedron Letters, 53. pp. 4858-4861. |
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| Relation |
http://ihbt.csircentral.net/1233/
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