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Effects of alternating and direct current in electrocoagulation process on the removal of cadmium from water

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title Effects of alternating and direct current in electrocoagulation process on the removal of cadmium from water
 
Creator Vasudevan, S.
Lakshmi, J.
Sozhan, G.
 
Subject Electroinorganic
 
Description In practice, direct current (DC) is used in an electrocoagulation processes. In this case, an impermeable oxide layer may form on the cathode as well as corrosion formation on the anode due to oxidation. This prevents the effective current transfer between the anode and cathode, so the efficiency of electrocoagulation processes declines. These disadvantages of DC have been diminished by adopting alternating current (AC) in electrocoagulation processes. The main objective of this study is to investigate the effects of AC and DC on the removal of cadmium from water using aluminum alloy as anode and cathode. The results showed that the removal efficiency of 97.5 and 96.2% with the energy consumption of 0.454 and 1.002 kWh kl−1 was achieved at a current density of 0.2 A/dm2 and pH of 7.0 using aluminum alloy as electrodes using AC and DC, respectively. For both AC and DC, the adsorption of cadmium was preferably fitting Langmuir adsorption isotherm, the adsorption process follows second order kinetics and the temperature studies showed that adsorption was exothermic and spontaneous in nature
 
Publisher Elsevier
 
Date 2011
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/2908/1/093-2011.pdf
Vasudevan, S. and Lakshmi, J. and Sozhan, G. (2011) Effects of alternating and direct current in electrocoagulation process on the removal of cadmium from water. Journal of Hazardous Materials, 192 (001). pp. 26-34. ISSN 0304-3894
 
Relation http://cecri.csircentral.net/2908/