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Controlling the assembly of hydrophobized gold nanoparticles at the air–water interface by varying the interfacial tension

IR@NPL: CSIR-National Physical Laboratory, New Delhi

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Title Controlling the assembly of hydrophobized gold nanoparticles at the air–water interface by varying the interfacial tension
 
Creator Gupta, Shweta
Singh , Nahar
Sastry, Murali
Kakkar , Rita
Pasricha, Renu
 
Subject Materials Science
Physics
 
Description Controlled assembly is the key to harness the nanoscale properties of nanoparticles in most technological applications and it has been an important challenge as it leads to the manipulation of interparticle properties. The present work depicts the control of the assembly of nanoparticles in the monolayers by evaporation kinetics and particle interactions at the air–liquid interface. In the presence of attractive particle–particle and particle–monolayers interactions, nanoparticles self assemble into a superlattice structure upon drying from a colloidal suspension on to the preformed lipid monolayers. This self-assembly mechanism produces monolayers with long-range ordering. However, rapid dewetting and high rate of evaporation can significantly undermine the extent of ordering. Using gold nanoparticles as vehicles for experimentation and by changing the monolayers and solvent, we here demonstrate that the extent of ordering of nanoparticles can be controlled.
 
Publisher Elsevier
 
Date 2010-08-20
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://npl.csircentral.net/59/1/47.pdf
Gupta, Shweta and Singh , Nahar and Sastry, Murali and Kakkar , Rita and Pasricha, Renu (2010) Controlling the assembly of hydrophobized gold nanoparticles at the air–water interface by varying the interfacial tension. Thin Solid Films, 519 (3). pp. 1072-1077. ISSN 0040-6090
 
Relation http://dx.doi.org/10.1016/j.tsf.2010.08.046
http://npl.csircentral.net/59/