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Doped Pr0.7−xBixSr0.3MnO3 manganite: A structural, electrical and magnetic effect

IR@NPL: CSIR-National Physical Laboratory, New Delhi

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Title Doped Pr0.7−xBixSr0.3MnO3 manganite: A structural, electrical and magnetic effect
 
Creator Kumar, Neeraj
H. , Kishan
Rao, A.
Awana, V. P. S.
 
Subject Chemistry
Materials Science
Metallurgy & Metallurgical Engineering
 
Description Structural, electrical and magnetic properties of Pr0.7−xBixSr0.3MnO3 (x = 0.00, 0.15, 0.25) compound have been studied. A decrease in unit cell volume is observed, although Bi3+ (1.17 Å) ion has larger ionic radii than Pr3+ (1.126 Å) ion and can be understood in a scenario of coexistence of charge ordered and ferromagnetic phase. “Electrical-resistivity and Magnetic” measurements show that the transition temperature (TMI, TC) increases i.e. “284.6 K, 276.5 K” to “294.04 K, ∼300 K” for Pr0.70Sr0.3MnO3 and Pr0.45Bi0.25Sr0.3MnO3 compounds, respectively. Larger ionic size of Bi3+ ion encourages double-exchange (DE) interaction, which in turns result an increase in transition temperatures.
 
Publisher Elsevier
 
Date 2010-06-01
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://npl.csircentral.net/91/1/66.pdf
Kumar, Neeraj and H. , Kishan and Rao, A. and Awana, V. P. S. (2010) Doped Pr0.7−xBixSr0.3MnO3 manganite: A structural, electrical and magnetic effect. Journal of Alloys and Compounds, 504 (2). L39-L41. ISSN 0925-8388
 
Relation http://dx.doi.org/10.1016/j.jallcom.2010.06.011
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