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Experimental investigations of semi-crystalline plasma polymerized polypyrrole for surface coating

IR@NPL: CSIR-National Physical Laboratory, New Delhi

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Title Experimental investigations of semi-crystalline plasma polymerized polypyrrole for surface coating
 
Creator Dhillon, Anju
Kaur, Amarjeet
Srivastava, A. K.
Avasthi, D. K.
 
Subject Chemistry
Materials Science
 
Description Plasma polymerized thin film of conducting polypyrrole were deposited at room temperature by plasma enhanced chemical vapor deposition method using pyrrole monomer as precursor. The radio frequency (RF: 13.56 MHz, power supply: 30 W) was applied at constant argon gas pressure for the formation of plasma. The as grown thin films of polypyrrole have been characterized by ellipsometry, Fourier transform infrared spectroscopy (FTIR), UV–vis spectroscopy, atomic force microscopy (AFM), X-ray diffractometry (XRD) and high-resolution transmission electron microscopy (HRTEM). UV–vis spectra showed the optical energy band gap of 2.3 eV. XRD pattern of plasma polymerized polypyrrole has revealed a clear peak at inter-planer separation of 0.687 nm. It was also noticed by HRTEM analysis that the distinguished reflection at d = 0.687 nm has a broadening effect that may be correlated with the crystallinity of the material.
 
Publisher Elsevier
 
Date 2010-08-05
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://npl.csircentral.net/152/1/125.pdf
Dhillon, Anju and Kaur, Amarjeet and Srivastava, A. K. and Avasthi, D. K. (2010) Experimental investigations of semi-crystalline plasma polymerized polypyrrole for surface coating. Progress in Organic Coatings, 69 (4). pp. 396-401. ISSN 0300-9440
 
Relation http://dx.doi.org/10.1016/j.porgcoat.2010.08.002
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