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Near UV emission and p-type conductivity in Zn1−xLixO and Zn1−xNaxO nanomaterial system

IR@NPL: CSIR-National Physical Laboratory, New Delhi

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Title Near UV emission and p-type conductivity in Zn1−xLixO and Zn1−xNaxO nanomaterial system
 
Creator Chawla, Santa
K. , Jayanthi
Khan, Zahid H.
Shah, Jyoti
Kotnala, R. K.
 
Subject Materials Science
 
Description The nanomaterial system Zn1−xLixO and Zn1−xNaxO (0<x<0.15) were synthesized by controlled solid state reaction. XRD analysis showed well formed wurtzite structure of average particle size about 50 nm and change in lattice parameters due to incorporation of group I element in ZnO lattice. SEM exhibited formation of nanorods. Hall effect measurement of Zn1−xLixO and Zn1−xNaxO system showed p-type conductivity which varied with concentration of Li and Na. Photoluminescence showed strong emission peak in near UV at 3.11 eV (398 nm) and negligible visible emission. The PL peak positions in Zn1−xLixO and Zn1−xNaxO nearly coincide which suggest very similar recombination mechanism in Li and Na doped ZnO nanocrystals. The results hold potential for fabrication of ZnO based near UV LEDs.
 
Publisher Elsevier
 
Date 2009-05-30
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://npl.csircentral.net/258/1/223.pdf
Chawla, Santa and K. , Jayanthi and Khan, Zahid H. and Shah, Jyoti and Kotnala, R. K. (2009) Near UV emission and p-type conductivity in Zn1−xLixO and Zn1−xNaxO nanomaterial system. Materials & Design , 31 (4). pp. 1666-1670. ISSN 0261-3069
 
Relation http://dx.doi.org/10.1016/j.matdes.2009.05.048
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