A Comparative Study Of Oxygen Loss On In Situ Heating In Prmno3 And Bamno3
IR@NPL: CSIR-National Physical Laboratory, New Delhi
View Archive Info| Field | Value | |
| Title |
A Comparative Study Of Oxygen Loss On In Situ
Heating In Prmno3 And Bamno3
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| Creator |
Garg , K. B.
Heinonen , M. Nordblad, P. Dalela, S. D. Panwar, N. Sen, V. Agarwal, S. K. Sharma, Neha |
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| Subject |
Applied Physics/Condensed Matter
Physics |
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| Description |
We have thoroughly investigated the oxygen loss in PrMnO3 and BaMnO3 , the end members of the AMnO3 system, on in situ heating in a reducing atmosphere. This
was done to drive some oxygen out from them and thus possibly alter the valence of the Mn cation. Sample characterization was done through X-ray diffraction and SEM
measurements. The core-level photoemission point to oxygen loss from only BaMnO3 changing some of Mn4+ to Mn3+ in it, transfer of some spectral weight to the highly
localized Fehrenbacher–Rice states and an increased Mn 3d–O 2p hybridization. Magnetization measurements show that at low temperatures, the samples depict a canted antiferromagnetic ordering.
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| Publisher |
World Scientific
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| Date |
2010-01-31
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://npl.csircentral.net/773/1/2.pdf
Garg , K. B. and Heinonen , M. and Nordblad, P. and Dalela, S. D. and Panwar, N. and Sen, V. and Agarwal, S. K. and Sharma, Neha (2010) A Comparative Study Of Oxygen Loss On In Situ Heating In Prmno3 And Bamno3. International Journal of Modern Physics B, 25 (9). pp. 1235-1250. ISSN 0217-9792 |
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| Relation |
http://dx.doi.org/10.1142/S0217979211058651
http://npl.csircentral.net/773/ |
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