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Combustion synthesized nanocrystalline Li3V2(PO4)3/C cathode for lithium-ion batteries

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title Combustion synthesized nanocrystalline Li3V2(PO4)3/C cathode for lithium-ion batteries
 
Creator Nathiya, K.
Bhuvaneswari, D.
Gangulibabu, .
Kalaiselvi, N.
 
Subject Lithium batteries
Electrochemical Power Sources
 
Description Nanocrystalline Li3V2(PO4)3/C composite synthesized using a novel corn assisted combustion method at 850 8C exhibits superior physical and electrochemical properties than the one synthesized at 800 8C. Despite the charge disproportionation of V4+ and a possible solid solution behavior of Li3V2(PO4)3 cathode upon insertion and extraction of Li+ ions, the structural stability of the same is appreciable, even with the extraction of third lithium at 4.6 V. An appreciable specific capacity of 174 mAh g�1 and better capacity retention upon high rate applications have been exhibited by Li3V2(PO4)3/C cathode, thus demonstrating the suitability of the same for lithium-ion battery applications
 
Publisher Elsevier Ltd.
 
Date 2012
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/3015/1/007-2012.pdf
Nathiya, K. and Bhuvaneswari, D. and Gangulibabu, . and Kalaiselvi, N. (2012) Combustion synthesized nanocrystalline Li3V2(PO4)3/C cathode for lithium-ion batteries. Materials Research Bulletin, 47. pp. 4300-4304. ISSN 0025-5408
 
Relation http://www.elsevier.com/locate/matresbu
http://cecri.csircentral.net/3015/