Cycling profile of MgAl2O4-incorporated composite electrolytes composed of PEO and LiPF6 for lithium polymer batteries
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
View Archive Info| Field | Value | |
| Title |
Cycling profile of MgAl2O4-incorporated composite electrolytes composed of PEO and LiPF6 for lithium polymer batteries
|
|
| Creator |
Angulakshmi, N.
Nahm, K.S. Nair, J.R. Gerbaldi, C. Bongiovanni, R. |
|
| Subject |
Lithium batteries
Electrochemical Power Sources |
|
| Description |
Magnesium aluminate (MgAl2O4)-incorporated poly(ethylene oxide) (PEO)–lithium hexafluorophosphate
(LiPF6) based composite polymer electrolyte (CPE) membranes were prepared by a hot press for
the first time. The membranes were subjected to X-ray diffraction (XRD), scanning electron microscopy
(SEM), thermogravimetric (TG), differential scanning calorimetry (DSC), tensile, impedance spectroscopy,
compatibility and transport number studies. The incorporation of MgAl2O4 greatly enhanced the ionic
conductivity, compatibility and mechanical integrity of the polymeric membrane. Finally, an all solid state
lithium cell composed of Li/CPE/LiFePO4 was assembled and its cycling profile was analyzed at 70 ◦C. The
cells delivered a discharge capacity of 127 mAh g−1 at 1 C-rate with very good capacity retention up to
100 cycles which is found to be better than those reported earlier
|
|
| Publisher |
Elsevier
|
|
| Date |
2013-02-15
|
|
| Type |
Article
PeerReviewed |
|
| Format |
application/pdf
|
|
| Identifier |
http://cecri.csircentral.net/3023/1/007-2013.pdf
Angulakshmi, N. and Nahm, K.S. and Nair, J.R. and Gerbaldi, C. and Bongiovanni, R. (2013) Cycling profile of MgAl2O4-incorporated composite electrolytes composed of PEO and LiPF6 for lithium polymer batteries. Electrochimica Acta, 90. pp. 179-185. ISSN 0013-4686 |
|
| Relation |
http://www.elsevier.com/locate/electacta
http://cecri.csircentral.net/3023/ |
|