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Effective Synthesis of Well-Graphitized Carbon Nanotubes on Bimetallic SBA-15 Template for Use as Counter Electrode in Dye-Sensitized Solar Cells

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title Effective Synthesis of Well-Graphitized Carbon Nanotubes on Bimetallic SBA-15 Template for Use as Counter Electrode in Dye-Sensitized Solar Cells
 
Creator Balamurugan, J.
Pandurangan, A.
Thangamuthu, R.
Senthilkumar, S.
 
Subject Electrochemical Materials Science
 
Description The fabrication of dye-sensitized solar cells (DSSCs) using well-graphitized carbon nanotubes (CNTs) as a counter electrode has been described in this study. The well-graphitized CNTs were synthesized at different temperatures (700, 800, and 900 °C) using bimetallic Fe-V catalyst supported on Santa Barbara Amorphous-15 (SBA-15). The molecular ratios between the two metals were varied in the catalytic template, and their effect on the distribution of the synthesized CNTs was studied. Cyclic voltammetry and electrochemical impedance spectroscopy revealed that the CNTs had higher electrochemical activity for the I3 −/I− redox reaction and a smaller charge transfer resistance than the platinum (Pt) electrode. Energy conversion efficiency of the CNTs was compared with Pt counter electrode. These results indicated that the CNTs have high surface conductivity, high active surface area, and good catalytic activity and can potentially replace Pt as counter electrode for application in DSSCs
 
Publisher American Chemical Society
 
Date 2013
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/3037/1/044-2013.pdf
Balamurugan, J. and Pandurangan, A. and Thangamuthu, R. and Senthilkumar, S. (2013) Effective Synthesis of Well-Graphitized Carbon Nanotubes on Bimetallic SBA-15 Template for Use as Counter Electrode in Dye-Sensitized Solar Cells. Industrial & Engineering Chemistry Research, 52. pp. 384-393.
 
Relation http://cecri.csircentral.net/3037/