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Thermal and Rheological Behavior of Ultrafine Fly Ash Filled LDPE Composites

IR@AMPRI: CSIR-Advanced Materials and Processes Research Institute, Bhopal

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Title Thermal and Rheological Behavior of Ultrafine Fly Ash Filled LDPE Composites
 
Creator Dr., S A R Hashmi
Dr., Pratibha Sharma
Navin, Chand
 
Subject Polymeric Materials
 
Description The specimens containing different volume fractions of ultrafine fly ash in LDPE were prepared with the help of two roll mixing mill and the hot-plate compression- molding machine. Thermal and rheological properties were evaluated using DSC and parallel-plate rotational- rheometer. The effect of composition variation on melt enthalpy, crystallinity, shear viscosity, shear stress and first normal stress difference was studied and reported here. The addition of ultrafine fly ash in LDPE decreased the melt enthalpy of the specimen. Slight decrease in the crystallinity of LDPE was observed on addition of fly ash. The shear stress as well as the shear viscosity both increased with the addition of ultrafine fly ash in LDPE. Two regions of shear thinning were observed at 2008C for fly ash filled LDPE. The first normal stress difference (N1) reduced with fly ash content and with the increased temperature. The values of N1 remained almost invariable at low shear region however a proportional increase was observed beyond the shear stress of 10 kPa.
 
Publisher Wiley Online Library
 
Date 2008
 
Type Article
PeerReviewed
 
Identifier Dr., S A R Hashmi and Dr., Pratibha Sharma and Navin, Chand (2008) Thermal and Rheological Behavior of Ultrafine Fly Ash Filled LDPE Composites. Journal of Applied Polymer Science, 107. pp. 2196-2202. ISSN 0021-8995
 
Relation http://ampri.csircentral.net/27/