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Attenuation of divalent toxic metal ions using natural sericitic pyrophyllite.

IR@AMPRI: CSIR-Advanced Materials and Processes Research Institute, Bhopal

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Title Attenuation of divalent toxic metal ions using natural sericitic pyrophyllite.
 
Creator Murari, Prasad
Sona, Saxena
 
Subject Environmental Studies/Chemistry
 
Description The present study investigated the effectiveness of an inexpensive and ecofriendly alumino silicate clay mineral, sericitic pyrophyllite, as an adsorbent for the possible application in the removal of some divalent toxic metal cations such as Pb2+, Cu2+and Zn2+ from aqueous systems. Batch scale equilibrium adsorption studies were carried out for a wide range of initial concentration from 24.1 to 2410 mmol L�1 for lead, 78.65 to 7865 mmol L�1 for copper and 76.45 to 7645 mmol L�1 for zinc solutions. The removal of Pb2+ was almost complete at low concentration (maximum lead removal capacity, LRC, 32 mg of lead/g of pyrophyllite) with 10 g L�1 of adsorbent in a 30 min equilibration time. The effects of temperature on adsorption of heavy metal ions were studied. The applicability of the Langmuir, Freundlich and Dubinin–Radushkevich adsorption models in each case of lead, copper and zinc adsorption was examined separately at different temperatures. The adsorption process was found to be endothermic and the Freundlich adsorption model was found to represent the data at different temperatures more suitably.
 
Publisher ELSEVIER
 
Date 2008
 
Type Article
PeerReviewed
 
Identifier Murari, Prasad and Sona, Saxena (2008) Attenuation of divalent toxic metal ions using natural sericitic pyrophyllite. Journal of Environmental Management, 88. pp. 1273-1279. ISSN 0301-4797
 
Relation http://ampri.csircentral.net/165/