An Unusual Diastereoselective Pictet–Spengler Reaction: Synthesis of Novel Tetrahydro-β-Carboline Glycosides
IR@IICB: CSIR-Indian Institute of Chemical Biology, Kolkata
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| Title |
An Unusual Diastereoselective Pictet–Spengler Reaction: Synthesis of Novel Tetrahydro-β-Carboline Glycosides
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| Creator |
Pradhan, Prasun K
Nandi, Debkumar Das Pradhan, Soma Jaisankar, Parasuraman Giri, V S |
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| Subject |
Chemistry
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| Description |
An unusual kinetic approach to the Pictet–Spengler reaction
was investigated, in which L- or D-tryptophan methyl ester
reacted with aldehydes of 1,2-O-cyclohexylidene-3-allyloxy-α-Dxylofuranose, yielding exclusively the cis or trans diastereomer of tetrahydro-β-carboline glycoside, respectively, with complete stereocontrol.
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| Date |
2013
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://www.eprints.iicb.res.in/1975/1/SYNLETT__Volume_24_(_1_)__Pages_85%2D89;2013[137].pdf
Pradhan, Prasun K and Nandi, Debkumar and Das Pradhan, Soma and Jaisankar, Parasuraman and Giri, V S (2013) An Unusual Diastereoselective Pictet–Spengler Reaction: Synthesis of Novel Tetrahydro-β-Carboline Glycosides. Synlett, 24 (1). pp. 85-89. |
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| Relation |
http://www.eprints.iicb.res.in/1975/
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