Novel mixed hydroxy-carbonate precursor assisted synthetic technique for LiNi1/3Mn1/3Co1/3O2 cathode materials
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
View Archive Info| Field | Value | |
| Title |
Novel mixed hydroxy-carbonate precursor assisted synthetic technique for LiNi1/3Mn1/3Co1/3O2 cathode materials
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| Creator |
Manikandan, P.
Periasamy, P. |
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| Subject |
Lithium batteries
Electrochemical Power Sources |
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| Description |
Novel mixed hydroxy-carbonate (MHC) precursors were used to synthesis technique of LiNi1/3Mn1/3Co1/
3O2 cathode material. The powder X-ray diffraction (XRD) pattern of the synthesized LiNi1/3Mn1/3Co1/3O2
cathode materials exhibited a hexagonal cell with a = 2.8535 A˚ and c = 14.2040 A˚ . Fourier transform
infrared spectroscopy (FT-IR) spectrum of MHC and LiNi1/3Mn1/3Co1/3O2 consistent with vibration
modes of functional group. Presence of sub-micrometer particle size (200 nm) and highly crystalline
morphology confirmed using scanning electron microscopy (SEM). X-ray photoelectron spectroscopy
(XPS) suggested that oxidation state of the transition metals; Ni in +2, Mn in +4 and Co in +3 states,
respectively in LiNi1/3Mn1/3Co1/3O2 cathode materials. Cyclic voltammograms (CV) revealed only one
major redox couple at 4 V and suggested the absence of structural transitions from hexagonal to
monoclinic structure. The Li vs. LiNi1/3Mn1/3Co1/3O2 cell delivered an initial discharge capacity of
175 mAh g�1 in the voltage range 2.5–4.6 V @ 0.1 C.
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| Publisher |
Elsevier Ltd.
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| Date |
2014
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cecri.csircentral.net/3047/1/001-2014.pdf
Manikandan, P. and Periasamy, P. (2014) Novel mixed hydroxy-carbonate precursor assisted synthetic technique for LiNi1/3Mn1/3Co1/3O2 cathode materials. Materials Research Bulletin, 50. pp. 132-140. ISSN 0025-5408 |
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| Relation |
http://www.elsevier.co m/locate/matresbu
http://cecri.csircentral.net/3047/ |
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