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Superhydrophobicity on transparent fluorinated ethylene propylene films with nano-protrusion morphology by Ar+O2 plasma etching: Study of the degradation in hydrophobicity after exposure to the environment

IR@NAL: CSIR-National Aerospace Laboratories, Bangalore

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Title Superhydrophobicity on transparent fluorinated ethylene propylene films with nano-protrusion morphology by Ar+O2 plasma etching: Study of the degradation in hydrophobicity after exposure to the environment
 
Creator Gupta, Nitant
Kavya, M V
Singh, Yogesh
Jyothi, J
Barshilia, Harish C
 
Subject Aeronautics (General)
General
 
Description Fluorinated ethylene propylene (FEP) films were made superhydrophobic by Ar + O2 plasma etching process. Field emission scanning electron microscopy and atomic force microscopy studies of the plasma-treated FEP samples detected the presence of uniformly distributed nano-protrusions exhibiting a low surface roughness necessary for maintaining the transparency of the samples. In fact, optical transmittance measurements showed an improvement in the transparency of FEP samples after plasma treatment. The X-ray photoelectron spectroscopic analysis showed the presence of –CF x –O–CF x – (x = 1, 2, or 3) linkages in both untreated and plasma-treated samples which explains the hydrophilic nature (contact angle below 90∘) of the untreated sample. Fourier transform infrared spectroscopy showed no changes in the bulk properties of the plasma-treated samples. Moreover, exposure to the environment caused the surfaces to lose their superhydrophobic property in an indefinite amount of time. This has been further studied through a water immersion experiment and explained through the wetting state transition from Cassie state to Wenzel state.
 
Publisher American Institute of Physics
 
Date 2013
 
Type Journal Article
PeerReviewed
 
Format application/pdf
 
Identifier http://nal-ir.nal.res.in/11833/1/ja483.pdf
Gupta, Nitant and Kavya, M V and Singh, Yogesh and Jyothi, J and Barshilia, Harish C (2013) Superhydrophobicity on transparent fluorinated ethylene propylene films with nano-protrusion morphology by Ar+O2 plasma etching: Study of the degradation in hydrophobicity after exposure to the environment. Journal of Applied Physics, 114 . p. 164307. ISSN 0021-8979
 
Relation http://scitation.aip.org/content/aip/journal/jap/114/16/10.1063/1.4826897
http://nal-ir.nal.res.in/11833/