[Bmim]BF4-immobilized rhenium-catalyzed highly efficient oxygenation of aldimines to oxaziridines using solid peroxides as oxidants
IR@IIP: CSIR-Indian Institute of Petroleum, Dehradun
View Archive Info| Field | Value | |
| Creator |
Jain, Suman L
Singhal, Sweety Sain, Bir |
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| Date |
2009-06-19T10:40:40Z
2009-06-19T10:40:40Z 2009-06-19T10:40:40Z |
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| Identifier |
http://hdl.handle.net/123456789/209
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| Description |
Various rhenium-based catalysts immobilized in [bmim]BF4 were found to be efficient for oxygenation of various aldimines to the
corresponding oxaziridines in excellent yields under mild conditions using solid peroxides like UHP, SPC and SPB as oxidants. Among
the various rhenium-based catalysts studied, MTO was found to be most efficient. The reusability and recyclability of MTO immobilized
in [bmim]BF4 was established by using it for three subsequent cycles for oxygenation of benzylidine-tert-butylamine using UHP as
oxidant.
Keywords: Ionic liquid; Rhenium; Oxygenation; Aldimine; Solid oxidants
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| Language |
en_US
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| Subject |
Ionic liquid
Rhenium Oxygenation Aldimine Solid oxidants |
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| Title |
[Bmim]BF4-immobilized rhenium-catalyzed highly efficient oxygenation of aldimines to oxaziridines using solid peroxides as oxidants
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| Type |
Article
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