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Ruthenium Catalyzed Oxidation of 1,2-Diols to 1,2-Diketones Using Bromamine-T as an Oxidizing Agent

IR@IIP: CSIR-Indian Institute of Petroleum, Dehradun

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Field Value
 
Creator Jain, Suman L
Sharma, Vishal B
Sain, Bir
 
Date 2009-06-22T03:57:36Z
2009-06-22T03:57:36Z
2009-06-22T03:57:36Z
 
Identifier http://hdl.handle.net/123456789/214
 
Description A variety of 1,2-diols were selectively oxidized to their corresponding 1,2- diketones with bromamine-T using RuCl3 . xH2O as catalyst in alkaline acetonitrile/ water (1 : 1) medium. The reaction was pH dependent (pH 8.4), and at higher pH the rate of the reaction decreased significantly. Keywords: Bromamine-T, 1,2-diketones, 1,2-diols, oxidation, ruthenium chloride
 
Language en_US
 
Subject Oxidation
Bromamine-T
ruthenium chloride
1,2-diketones
 
Title Ruthenium Catalyzed Oxidation of 1,2-Diols to 1,2-Diketones Using Bromamine-T as an Oxidizing Agent
 
Type Article