Structural characterization of coke on spent hydroprocessing catalysts used for processing of vacuum gas oils
IR@IIP: CSIR-Indian Institute of Petroleum, Dehradun
View Archive Info| Field | Value | |
| Creator |
Sahoo, Sangrama K
Ray, Siddharth S Singh, I D |
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| Date |
2009-06-22T10:53:22Z
2009-06-22T10:53:22Z 2009-06-22T10:53:22Z |
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| Identifier |
http://hdl.handle.net/123456789/236
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| Description |
The molecular structure and composition of carbonaceous deposits commonly known as coke deposited inside the pores and on the surface
of aged hydroprocessing (hydrotreating and hydrocracking) catalysts in value upgradation of vacuum gas oils were investigated by various
analytical methods, such as NMR, HPLC and TGA. The soft (dichloromethane extractable) and hard (solvent insoluble) coke deposits from
two spent hydrotreating catalysts (CoMo/g-Al2O3 and NiMo/g-Al2O3) and one spent commercial hydrocracking catalyst with carbon
contents ranging from 5 to 10% were characterized. HPLC and high resolution liquid state 1H and 13C NMR methods were used for the
characterization of the soft coke whereas hard insoluble coke deposits were characterized by high resolution solid-state 13C NMR and TGA.
The results indicate that the composition of soft coke is mostly alkylated mono-, di-aromatics and fewer amounts of polyaromatics. The
composition of the hard coke in spent hydrotreating catalysts is relatively high in aliphatic content with high H/C ratio obtained in the present
study unlike the highly aromatic coke obtained with residue hydrotreating as reported in the literature. However, the insoluble coke deposits in
spent hydrocracking catalysts are highly aromatic in nature (aromaticity, fa > 0.95).
Keywords: Coke; Deactivation; Hydroprocessing; Catalyst; NMR
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| Language |
en_US
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| Subject |
NMR
Deactivation Hydroprocessing Catalyst Coke |
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| Title |
Structural characterization of coke on spent hydroprocessing catalysts used for processing of vacuum gas oils
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| Type |
Article
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