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AN INVESlIGATION ON THE INFLUENCE OF CHEMICAL STRUCTURE ON ADDIliVE PERFORMANCE

IR@IIP: CSIR-Indian Institute of Petroleum, Dehradun

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Creator Shukla,D.S
Sharma,V.P
Bisht,R.P.S
Shukla,B.M
Nautiyal,P.C
 
Date 2009-07-10T05:33:13Z
2009-07-10T05:33:13Z
2009-07-10T05:33:13Z
 
Identifier http://hdl.handle.net/123456789/312
 
Description The performance of additive molecule is gover-ned by its chemical structure as wel~ as the type of elements present in it. Tho ugh, S E\.e ,- a 1 i n v est i gat Ion S h a \,. e been con due t e d t hE' world over in thIs area, yet, exact mode c~ additive intet-action I~ not fully addt-essed. To undet-stand this, a study was undertaken on the perfQrmance behavior of additives containing sulphut-, phosphot-ous' as actIve elements having differ-ent chemicCtl structut-es. It is obset-ved that even though the sulphut- level i~. the sarne for different additives in the blends, their perfOt'mance differed markedly, cleat-ly indicating the.t the chemical structure of the additive a f fee t e d i t ~. pet' f 0 t-m Ctnee be h a v i 0 ,- s i 9 n i f i c a ~, t 1 y . The t es t par am e t e t-s \-.e1 t'E S EO 1 E?C t e d bas E'd 0 r, thE' 0 r e tic d ] c ,-,input a t i 0 r't cd contact stresses, film thIcknesses etc. to render an effective discrimination of performance results of the additives. The additives were evaluated by 4-Ball extreme pressure (EP) testing machine as we11 as by shoc k load test developed at authors laboratory for evaluation of shock load tendency of gear oils using Amsler friction and wear machine. This paper discusses the effect of dose-response relationship of different chemical structures employed in the oil system. It is seen that the chemical structut-e of the additives governs the tribological J2ehavior greatly and controls the failure phenomenon.
 
Language en_US
 
Subject Gear oils
 
Title AN INVESlIGATION ON THE INFLUENCE OF CHEMICAL STRUCTURE ON ADDIliVE PERFORMANCE
 
Type Article