METAL PHTHALOCYANINE CATALYZED OXIDATION OF ORGANIC SUBSTRATES WITH DIOXYGEN - ALDEHYDE SYSTEM
IR@IIP: CSIR-Indian Institute of Petroleum, Dehradun
View Archive Info| Field | Value | |
| Creator |
Rao,V.T
Sain,Bir Murthy,P.S.N Joshi,G.C Prasada Rao,T.S.R |
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| Date |
2009-07-16T10:52:02Z
2009-07-16T10:52:02Z 2009-07-16T10:52:02Z |
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| Identifier |
Recent Advances in Basic and Applied Aspects of Industrial Catalysis Studies in Surface Science and Catalysis, Vol. 113
http://hdl.handle.net/123456789/353 |
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| Description |
Metal phthalocyanines have been found to catalyze the oxidation of sulphides to
sulphones at room temperature by molecular oxygen (1 atm) in the presence of
isobutyraldehyde as sacrificial aldehyde. Among the metal phthalocyanines studied those of
Fe(II), Mn(II) and Co(II)tetrasulphonato- showed excellent activity, followed by VO, while
those of Ni(II) and Cu(II) were found to be least active for sulfide oxidation.
Mn(II)phthalocyanine catalyzed epoxidation of olefins with molecular oxygen -
isobutyraldehyde systems is also reported.
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| Language |
en_US
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| Subject |
Heterogeneous Catalysis
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| Title |
METAL PHTHALOCYANINE CATALYZED OXIDATION OF ORGANIC SUBSTRATES WITH DIOXYGEN - ALDEHYDE SYSTEM
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| Type |
Article
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