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Kinetic study of free radical bulk copolymerization of styrene-methyl methacrylate

IR@IIP: CSIR-Indian Institute of Petroleum, Dehradun

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Field Value
 
Creator Khan,H.U
Wadehra,B.M.L
 
Date 2009-07-23T05:24:58Z
2009-07-23T05:24:58Z
2009-07-23T05:24:58Z
 
Identifier POLYMER, 1981, Vol 22, April
http://hdl.handle.net/123456789/376
 
Description In an attempt to reveal the kinetic mechanism of free radical bulk copolymerization of styrene-methyl methacrylate (SMMA), experiments were conducted in sealed glass ampules at constant temperature using benzoyl peroxide as catalyst. The analysis of the various experimental data for rate of polymerization and other parameters indicate that: (a) the rate of copolymerization is lower than the homopolymerization of pure styrene and methyl methacrylate (M MA), separately and decreases graduallywith increasing styrene content from ~ 0.2 to 0.9 molfraction in the feed; (b) the termination mechanism in SM MA copolymerization is controlled by diffusion.
 
Language en_US
 
Subject Waxes
 
Title Kinetic study of free radical bulk copolymerization of styrene-methyl methacrylate
 
Type Article