Liquid Phase Oxidation of s-Butyltoluene
IR@IIP: CSIR-Indian Institute of Petroleum, Dehradun
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Creator |
Kulsrestha,Girendra N
Pathania,Bikram Sharma,Krishna G Sharma,Jaipal S Negi,Janaki Bhattacharyya,K.K |
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Date |
2010-05-11T11:25:43Z
2010-05-11T11:25:43Z 2010-05-11T11:25:43Z |
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Identifier |
Indian Journal of Chemistry,Vol. 22A, July 1983, pp. 636-638
http://hdl.handle.net/123456789/518 |
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Description |
Oxidation of s"butyItoluene (SB1) to its hydroperoxide (ROOH)
by oxygen has been studied in the presence and absence of catalysts
in aqueous suspension at 80° to 116°C and 1 to 8.5 kg/cm2 O2
pressure. The oxidation rate is higher at higher pressures and the
selectivity to ROOH formation is the highest when no catalyst is
used. Effects of various reaction parameters have been studied inthe
absence of catalyst. A reactKm temperature of 100°, SBT -water ratio
of 1:2 and oxygen pressure of more than 3 kg/cm2 are found to be the
most suitable for ROOH formation. Oxidation above 11.5% ROOH
level leads mainly to byproducts including s-butylbenzoic acid.
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Language |
en_US
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Subject |
Liquid Phase
Oxidation s-Butytoluene |
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Title |
Liquid Phase Oxidation of s-Butyltoluene
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Type |
Article
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