The Kinetics of Catalytic Oxidation of 1-Butanethiol in a Gas Liquid System
IR@IIP: CSIR-Indian Institute of Petroleum, Dehradun
View Archive Info| Field | Value | |
| Creator |
Ganguly,S.K
Das,G Mohanty,B Bhargava,R Dawra,S |
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| Date |
2011-08-23T04:12:58Z
2011-08-23T04:12:58Z 2011-08-23T04:12:58Z |
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| Identifier |
http://hdl.handle.net/123456789/733
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| Description |
In the present study the kinetics of liquid phase oxidation of light thiols
using reformulated cobalt phthalocyanine based catalyst has been investigated in
a semi batch bubble column reactor. 1-Butanethiol is chosen to represent thiols in
lighter range of petroleum fractions like liquefied petroleum gas and light straight
run naphtha. The study has shown that rate of catalytic oxidation of 1-butanethiol is
linear at lower concentrations and of nonlinear nature at higher concentrations. A
mechanism based rate expression has been obtained to explain this behavior and its
parameters are estimated. The derived rate law is similar to Michaelis-Menten rate
equation.
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| Language |
en_US
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| Subject |
Catalytic Oxidation
Cobalt (II) phthalocyanine sulfonamide catalyst Kinetics Lineweaver-Burk plot Michaelis-Mentin rate equation Sweetening Thiols |
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| Title |
The Kinetics of Catalytic Oxidation of 1-Butanethiol in a Gas Liquid System
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| Type |
Article
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