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Molecular Iodine Mediated Domino Reaction for Synthesis of Benzamides, 2,2-diazidobenzofuran-3(2H)-ones and Benzoxazolones

IR@CDRI: CSIR-Central Drug Research Institute, Lucknow

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Field Value
 
Creator Rajendar, K
Kant, Ruchir
Narender, T
 
Date 2014-07-31T10:11:02Z
2014-07-31T10:11:02Z
2013
 
Identifier Advanced Synthesis & Catalysis, 2013, 355(18), 3591–3596
http://hdl.handle.net/123456789/1325
 
Description A simple and efficient domino protocol has been developed for the preparation of biologically important benzamides, 2,2-diazidobenzofuran-3(2H)-ones and benzoxazolones from various structurally and electronically divergent acetophenones and o-hydroxy acetophenones in the presence of molecular iodine, sodium azide and sodium bicarbonate at 100 °C in good to excellent yields.
 
Format 192949 bytes
application/pdf
 
Language en
 
Relation CSIR-CDRI Communication No. 8574
 
Subject Benzoxazolone
Benzamide
2,2-Diazidobenzofuran-3(2H)-One
Iodine
Sodium Azide
Curtius Rearrangement
Haller-Bauer Reaction
 
Title Molecular Iodine Mediated Domino Reaction for Synthesis of Benzamides, 2,2-diazidobenzofuran-3(2H)-ones and Benzoxazolones
 
Type Article