Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
View Archive Info| Field | Value | |
| Title |
Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic Organic
Chemistry
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|
| Creator |
Kulangiappar, K.
Anbukulandainathan, M. Raju, T. |
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| Subject |
Electroorganic
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| Description |
The electrochemical bromination of 4-methoxy toluene by two-phase electrolysis
yields 3-bromo 4-methoxy toluene at first, which subsequently undergoes side-chain bromination
to give 3-bromo 4-methoxy benzyl bromide as a final product in 86% yield. The
two-phase electrolysis consists of 25–50% NaBr as aqueous electrolyte and CHCl3 containing
aromatic compound as organic phase. The reaction temperature is maintained at
10–25 �C. The probable orientation of bromine atom in an alkyl aromatic compound
(nuclear versus side chain) is explained from the experimental result
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| Publisher |
Taylor & Francis
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|
| Date |
2014
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cecri.csircentral.net/3097/1/036-2014.pdf
Kulangiappar, K. and Anbukulandainathan, M. and Raju, T. (2014) Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry. Synthetic Communications, 1 (44). pp. 2494-2502. ISSN 0039-7911 |
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| Relation |
http://www.tandfonline.com/loi/lsyc20
http://cecri.csircentral.net/3097/ |
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