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Li4NiTeO6 as a positive electrode for Li-ion batteries

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title Li4NiTeO6 as a positive electrode for Li-ion batteries
 
Creator Sathiya, M.
Ramesha, K.
Rousse, G.
Foix, D.
Gonbeau, D.
Guruprakash, K.
Prakash, A.S.
Doubletef, M.L.
Tarascon, J.M.
 
Subject Lithium batteries
Electrochemical Power Sources
 
Description Layered Li4NiTeO6 was shown to reversibly release/uptake B2 lithium ions per formula unit with fair capacity retention upon long cycling. The Li electrochemical reactivitymechanism differs from that of Li2MO3 and is rooted in the Ni4+/Ni2+ redox couple, that takes place at a higher potential than conventional LiNi1�xMnxO2 compounds.We explain this in terms of inductive effect due to Te6+ ions (or the TeO6 6� moiety
 
Publisher Royal Society of Chemistry
 
Date 2013
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/3099/1/091-2013.pdf
Sathiya, M. and Ramesha, K. and Rousse, G. and Foix, D. and Gonbeau, D. and Guruprakash, K. and Prakash, A.S. and Doubletef, M.L. and Tarascon, J.M. (2013) Li4NiTeO6 as a positive electrode for Li-ion batteries. Chemical Communications, 49. pp. 11376-11378. ISSN 1359-7345
 
Relation http://www.rsc.org/chemcomm
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