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Nucleation of copper on mild steel in copper chloride (CuCl2�2H2O)–1-ethyl-3-methylimidazolium chloride [EMIM]Cl–ethylene glycol (EG) ionic liquid

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title Nucleation of copper on mild steel in copper chloride (CuCl2�2H2O)–1-ethyl-3-methylimidazolium chloride [EMIM]Cl–ethylene glycol (EG) ionic liquid
 
Creator Saravanan, G.
Mohan, S.
 
Subject Industrial Metal Finishing
 
Description A dense and adhesive Cu layer was successfully electrodeposited on mild steel in a copper chloride (CuCl2�2H2O)–1-ethyl-3-methylimidazolium chloride [EMIM]Cl–ethylene glycol [EG] ionic liquid. The mechanism of copper nucleation is studied using cyclic voltammetry and chronoamperometry. It is observed that 3D-instantaneous nucleation leads to a bright nano-structured deposit. The morphology of the deposit was characterized SEM and X-ray diffraction techniques. The deposition method was found to take place in an environmentally friendly green electrolyte without co-ligands such as cyanide and volatile toxic solvents
 
Publisher The Royal Society of Chemistry
 
Date 2013
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/3120/1/087-2013.pdf
Saravanan, G. and Mohan, S. (2013) Nucleation of copper on mild steel in copper chloride (CuCl2�2H2O)–1-ethyl-3-methylimidazolium chloride [EMIM]Cl–ethylene glycol (EG) ionic liquid. New Journal of Chemistry, 37. pp. 2564-2567. ISSN 1144-0546
 
Relation http://www.rsc.org/njc
http://cecri.csircentral.net/3120/