Nucleation of copper on mild steel in copper chloride (CuCl2�2H2O)–1-ethyl-3-methylimidazolium chloride [EMIM]Cl–ethylene glycol (EG) ionic liquid
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
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Title |
Nucleation of copper on mild steel in copper chloride
(CuCl2�2H2O)–1-ethyl-3-methylimidazolium chloride
[EMIM]Cl–ethylene glycol (EG) ionic liquid
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Creator |
Saravanan, G.
Mohan, S. |
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Subject |
Industrial Metal Finishing
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Description |
A dense and adhesive Cu layer was successfully electrodeposited on mild steel in a copper chloride
(CuCl2�2H2O)–1-ethyl-3-methylimidazolium chloride [EMIM]Cl–ethylene glycol [EG] ionic liquid. The mechanism
of copper nucleation is studied using cyclic voltammetry and chronoamperometry. It is observed that
3D-instantaneous nucleation leads to a bright nano-structured deposit. The morphology of the deposit was
characterized SEM and X-ray diffraction techniques. The deposition method was found to take place in an
environmentally friendly green electrolyte without co-ligands such as cyanide and volatile toxic solvents
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Publisher |
The Royal Society of Chemistry
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Date |
2013
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Type |
Article
PeerReviewed |
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Format |
application/pdf
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Identifier |
http://cecri.csircentral.net/3120/1/087-2013.pdf
Saravanan, G. and Mohan, S. (2013) Nucleation of copper on mild steel in copper chloride (CuCl2�2H2O)–1-ethyl-3-methylimidazolium chloride [EMIM]Cl–ethylene glycol (EG) ionic liquid. New Journal of Chemistry, 37. pp. 2564-2567. ISSN 1144-0546 |
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Relation |
http://www.rsc.org/njc
http://cecri.csircentral.net/3120/ |
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