Autocatalytic duplex Ni-P/Ni-W-P coatings on AZ 31B magnesium alloy
IR@NAL: CSIR-National Aerospace Laboratories, Bangalore
View Archive Info| Field | Value | |
| Title |
Autocatalytic duplex Ni-P/Ni-W-P coatings on AZ 31B magnesium alloy
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| Creator |
Ezhil Selvi, V
Balaraju, JN |
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| Subject |
Chemistry and Materials (General)
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| Description |
Autocatalytic duplex Ni-P/Ni-W-P coatings were deposited on AZ31B magnesium alloy using stabilizer free nickel carbonate bath. Some of the coated specimens were passivated in chromate solution with and without heat treatment. Plain Ni-P coatings were also prepared for comparison. Coatings were characterized for their surface morphology, composition and corrosion resistance. Energy dispersive analysis of X-ray (EDX) showed that the duplex coating contained about
3 wt.% P and 2 wt.% W with balance Ni. Marginal increase in P and W contents were observed on passivated coupons along with Cr (0.18 wt.%) and O (2.8 wt.%) contents. Field emission scanning electron microscopy (FESEM) examination of these coatings surfaces exhibited the nodular morphology. Chromate passivated surfaces showed the presence of uniformly distributed bright Ni particles along with nodules. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) studies were carried out in deaerated 0.15 M NaCl solution to find out the corrosion resistance of the coatings. Among the coatings developed, duplex-heat treated-passivated (duplex-HTP) coatings showed lower corrosion current density (icorr) and higher polarization resistance (Rp) indicating the improved corrosion resistance. The charge transfer resistance (Rct) value obtained for the duplex-HTP was about 170 times higher compared to Ni-P coating.
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| Publisher |
Elsevier Publisher
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| Date |
2013
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| Type |
Journal Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://nal-ir.nal.res.in/12046/1/ja453.pdf
Ezhil Selvi, V and Balaraju, JN (2013) Autocatalytic duplex Ni-P/Ni-W-P coatings on AZ 31B magnesium alloy. Surface and Coatings Technology, 240 . pp. 103-109. ISSN 0257-8972 |
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| Relation |
http://www.sciencedirect.com/science/article/pii/S0257897213011742
http://nal-ir.nal.res.in/12046/ |
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