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Equation of state of bcc-Mo by static volume compression to 410 GPa

IR@NAL: CSIR-National Aerospace Laboratories, Bangalore

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Title Equation of state of bcc-Mo by static volume compression to 410 GPa
 
Creator Yuichi, Akahama
Naohisa, Hirao
Yasuo, Ohishi
Singh, AK
 
Subject Chemistry and Materials (General)
 
Description Unit cell volumes of Mo and Pt have been measured simultaneously to ≈400 GPa by x-ray powder diffraction using a diamond anvil cell and synchrotron radiation source. The body-centered cubic (bcc) phase of Mo was found to be stable up to 410 GPa. The equation of state (EOS) of bcc-Mo was determined on the basis of Pt pressure scale. A fit of Vinet EOS to the volume compression data gave K 0 = 262.3(4.6) GPa, K 0′ = 4.55(16) with one atmosphere atomic volume V 0 = 31.155(24) A3. The EOS was in good agreement with the previous ultrasonic data within pressure difference of 2.5%–3.3% in the multimegabar range, though the EOS of Mo proposed from a shock compression experiment gave lower pressure by 7.2%–11.3% than the present EOS. The agreement would suggest that the Pt pressure scale provides an accurate pressure value in an ultra-high pressure range.
 
Publisher American Institute of Physics
 
Date 2014
 
Type Journal Article
PeerReviewed
 
Format application/pdf
 
Identifier http://nal-ir.nal.res.in/12055/1/2014_EOS_Mo_410GPa.pdf
Yuichi, Akahama and Naohisa, Hirao and Yasuo, Ohishi and Singh, AK (2014) Equation of state of bcc-Mo by static volume compression to 410 GPa. Journal of Applied Physics, 116 . ISSN 0021-8979
 
Relation http://scitation.aip.org/content/aip/journal/jap/116/22/10.1063/1.4903940
http://nal-ir.nal.res.in/12055/