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Role of amino acids on electrodeposition and characterisation of zinc from alkaline zincate solutions

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title Role of amino acids on electrodeposition and characterisation of zinc from alkaline zincate solutions
 
Creator Sekar, R.
Jagadesh, K.K.
Ramesh Bapu, G.N.K.
 
Subject Industrial Metal Finishing
 
Description Amino acid-based addition agents have been employed in an alkaline zincate plating electrolyte to modify corrosion resistance, crystal size, surface morphology, and adhesion of deposits. These addition agents such as guanine, histidine and glutamic acid are recommended in zincate solution to improve the corrosion resistance, crystal size and adhesion of the deposits. The XRD pattern obtained for electrodeposited zinc from such baths shows a polycrystalline hexagonal close-packed (hcp) structure. The crystal size was calculated using the Scherrer formula. A uniform and pore-free surface was observed under scanning electron microphotography (SEM) analysis. The corrosion resistance behaviour of the zinc deposits was analysed by potentiodynamic polarisation and electrochemical impedance spectroscopy (EIS). Histidine appears to show most promise in enhancing corrosion resistance and grain refining.
 
Date 2015
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/3139/1/003-2015.pdf
Sekar, R. and Jagadesh, K.K. and Ramesh Bapu, G.N.K. (2015) Role of amino acids on electrodeposition and characterisation of zinc from alkaline zincate solutions. Transactions of the Institute of Materials Finishing. (In Press)
 
Relation http://cecri.csircentral.net/3139/