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A highly efficient ultrasound-promoted synthesis of 2,3-disubstituted benzo[b]furans via intramolecular C-C bond formation in ionic liquid[bmim]BF4 at room temperature

IR@CDRI: CSIR-Central Drug Research Institute, Lucknow

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Field Value
 
Creator Yadav, Nisha
Hussain, M K
Ansari, M I
Gupta, P K
Hajela, Kanchan
 
Date 2013-09-30T11:45:32Z
2013-09-30T11:45:32Z
2013
 
Identifier RSC Advances, 2013, 3, 540-544
http://hdl.handle.net/123456789/1129
 
Description An efficient ultrasound promoted synthesis of 2, 3-disubstituted benzo[b]furans in the ionic liquid, [bmim]BF4 at room temperature is reported. 5-exo-dig carbanion-yne intramolecular cyclization is mediated using anhydrous K3PO4 as a mild, inexpensive base under atmospheric conditions giving the title benzo[b]furans in excellent yields. Ionic liquid [bmim]BF4 has been used both as reaction medium as well as catalyst for the C-C bond formation.
 
Format 122053 bytes
application/pdf
 
Language en
 
Relation CSIR-CDRI Communication No. 8352
 
Subject benzo[b]furans
intramolecular C-C bond
 
Title A highly efficient ultrasound-promoted synthesis of 2,3-disubstituted benzo[b]furans via intramolecular C-C bond formation in ionic liquid[bmim]BF4 at room temperature
 
Type Article