A highly efficient ultrasound-promoted synthesis of 2,3-disubstituted benzo[b]furans via intramolecular C-C bond formation in ionic liquid[bmim]BF4 at room temperature
IR@CDRI: CSIR-Central Drug Research Institute, Lucknow
View Archive InfoField | Value | |
Creator |
Yadav, Nisha
Hussain, M K Ansari, M I Gupta, P K Hajela, Kanchan |
|
Date |
2013-09-30T11:45:32Z
2013-09-30T11:45:32Z 2013 |
|
Identifier |
RSC Advances, 2013, 3, 540-544
http://hdl.handle.net/123456789/1129 |
|
Description |
An efficient ultrasound promoted synthesis of 2, 3-disubstituted benzo[b]furans in the ionic liquid, [bmim]BF4 at room temperature is reported. 5-exo-dig carbanion-yne intramolecular cyclization is mediated using anhydrous K3PO4 as a mild, inexpensive base under atmospheric conditions giving the title benzo[b]furans in excellent yields. Ionic liquid [bmim]BF4 has been used both as reaction medium as well as catalyst for the C-C bond formation.
|
|
Format |
122053 bytes
application/pdf |
|
Language |
en
|
|
Relation |
CSIR-CDRI Communication No. 8352
|
|
Subject |
benzo[b]furans
intramolecular C-C bond |
|
Title |
A highly efficient ultrasound-promoted synthesis of 2,3-disubstituted benzo[b]furans via intramolecular C-C bond formation in ionic liquid[bmim]BF4 at room temperature
|
|
Type |
Article
|
|