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Low-density three-dimensional foam using self-reinforced hybrid two-dimensional atomic layers

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title Low-density three-dimensional foam using self-reinforced hybrid two-dimensional atomic layers
 
Creator Soumya, V.
Tiwary, C.S.
Silva Autreto, P.
Taha-Tijerina, J.
Ozden, S.
Chipara, A.C.
Vajtai, R.
Galvao, D.S.
Narayanan, T.N.
Ajayan, P.M.
 
Subject Functional Materials
Electrochemical Materials Science
 
Description Low-density nanostructured foams are often limited in applications due to their low mechanical and thermal stabilities. Here we report an approach of building the structural units of three-dimensional (3D) foams using hybrid two-dimensional (2D) atomic layers made of stacked graphene oxide layers reinforced with conformal hexagonal boron nitride (h-BN) platelets. The ultra-low density (1/400 times density of graphite) 3D porous structures are scalably synthesized using solution processing method. A layered 3D foam structure forms due to presence of h-BN and significant improvements in the mechanical properties are observed for the hybrid foam structures, over a range of temperatures, compared with pristine graphene oxide or reduced graphene oxide foams. It is found that domains of h-BN layers on the graphene oxide framework help to reinforce the 2D structural units, providing the observed improvement in mechanical integrity of the 3D foam structure
 
Publisher Macmillan Publishers Limited
 
Date 2014
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/3149/1/055-2014.pdf
Soumya, V. and Tiwary, C.S. and Silva Autreto, P. and Taha-Tijerina, J. and Ozden, S. and Chipara, A.C. and Vajtai, R. and Galvao, D.S. and Narayanan, T.N. and Ajayan, P.M. (2014) Low-density three-dimensional foam using self-reinforced hybrid two-dimensional atomic layers. Nature Communications, 5. pp. 4541-4550. ISSN 2041-1723
 
Relation http://www.nature.com/naturecommunications
http://cecri.csircentral.net/3149/